Atomically Dispersed Au on In₂O₃ Nanosheets for Highly Sensitive and Selective Detection of Formaldehyde

Abstract

As an important industrial chemical, formaldehyde is used in various fields but is harmful to health. Developing a convenient detection device for formaldehyde is significant. Based on atomically dispersed Au on In₂O₃ nanosheets, a formaldehyde sensor was fabricated in this work. The highly dispersed Au obtained by the ultraviolet (UV) light-assisted reduction method helps improve the sensing performance. A meager loading amount (0.01 wt %) of Au on In₂O₃ nanosheets exhibits high sensitivity toward ppb-level formaldehyde. Au acts as an electron sink and promotes the oxidation of formaldehyde. Atomically dispersed Au on In₂O₃ nanosheets decreases the activation energy and increases the number of active sites, which result in a highly efficient conversion of formaldehyde and a marked resistance change of the fabricated sensors. The selective adsorption and oxidation of formaldehyde on single atom Au's uniform sites establish excellent selectivity. Besides, the sensor exhibits short response/recovery time and excellent stability, with promising applications in formaldehyde detection.