Na3PO4 assistant dispersion of nano-CaCO3 template to enhance electrochemical interface: N/O/P co-doped porous carbon hybrids towards high-performance flexible supercapacitors

Abstract

Recently porous carbon hybrids have attracted ever-increasing attention as electrode materials for supercapacitors, but it remains a great challenge to simultaneously control their pore structure and element composition with optimal electrochemical performances. Herein, Na 3 PO 4 assistant dispersion of nano-CaCO 3 template in egg white was proposed to fabricate nitrogen/oxygen/phosphorus (N/O/P) co-doped 3D hierarchical porous carbon hybrids. The as-prepared carbon exhibited a high surface area (2576 m 2 g 1 ), well-balanced pore size distribution with a large micropore volume (0.77 cm 3 g 1 ) and multi-heteroatoms doped carbon skeleton (3.9% of N, 12.2% of O and 4.1% of P). These physicochemical advantages were synergistically beneficial to supercapacitive performances: an ultrahigh capacitance of 452 F g 1 at 0.5 A g 1 in 6 M KOH electrolyte and excellent stability of 92.4% capacitance retention after 10000 cycles at 10 A g 1 . The energy density was 22.6 Wh kg 1 at the power density of 225.0 W kg 1 in the neutral electrolyte of 1 M Li 2 SO 4 . Especially, a flexible symmetric solidstate supercapacitor was assembled, which delivered a high capacitance (166 F g 1 ) and excellent flexibility (86.3% capacitance retention) with bending angles to 180 . Thus, this work provides a cost-effective strategy to fabricate multi-element co-doped 3D hierarchical porous carbon and expand its application for flexible energy storage devices.