Incorporating Trigonal-Prismatic Cobalt(II) Blocks into an Exchange-Coupled [Co₂Cu] System

Abstract

Taking advantage of a rigid tetradentate ligand of bis(pyrazoly)(3-pyrazolypyridinyl)methane (PyPz₃) and the [Cu^II(opba)]^2- unit [opba^4- = <i>o</i>-phenylenebis(oxamato)], the trinuclear complex [{Co^II(PyPz₃)}₂Cu^II(opba)][ClO₄]₂·5MeCN·MeOH (<b>1</b>) was constructed, in which the Co^II centers adopt a trigonal-prismatic geometry, while considerable intramolecular magnetic coupling was successfully introduced through the oxamido bridges, representing another very first example of single-molecule magnets marrying both selected coordination geometry and magnetic exchanges.