Publication | Closed Access
All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters
39
Citations
28
References
2020
Year
A series of POM-based all-inorganic open frameworks, H<sub>9</sub>[Ln<sub>9</sub>W<sub>8</sub>(μ<sub>4</sub>-O)<sub>12</sub>(μ<sub>2</sub>-O)<sub>24</sub>(H<sub>2</sub>O)<sub>24</sub>](SiW<sub>12</sub>O<sub>40</sub>)<sub>3</sub>·60H<sub>2</sub>O (1-Ln, Ln = La, Pr and Nd), have been fabricated and structurally characterized for the first time. The unique architectures are constructed from nanoscale four-shell Ln@W<sub>8</sub>@Ln<sub>8</sub>@(SiW<sub>12</sub>)<sub>6</sub> clusters. Additionally, the porous nature of the frameworks has also been investigated.
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