Chemical Communications · 2020 · 35 citations · 38 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryNanomaterialsNanotechnologyCluster ChemistryCluster CompoundsFluorescence SpectroscopyLuminescent MaterialsOrganic SemiconductorsFluorophore ChemistryLuminescent Coordination CompoundsLuminescent Nanomaterials
We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb6(μ3-F)8(piv)10(Hpiv)4DMF]·xDMF·yH2O 1. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.
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Near-unity photoluminescence quantum yield in MoS <sub>2</sub>
Matin Amani, Der‐Hsien Lien, Daisuke Kiriya et al. · Science · 2015 · 1.2K citations · Full text
Visible Quantum Cutting in LiGdF <sub>4</sub> :Eu <sup>3+</sup> Through Downconversion
R. T. Wegh, H. Donker, K.D Oskam et al. · Science · 1999 · 1.1K citations