ACS Omega · 2020 · 10 citations · 35 references
EngineeringChemical EngineeringChemistryReaction EngineeringSeparation ProcessesSeparation ScienceAdsorptive SeparationsSulfur ChemistryAvrami AnalysisAvrami EquationAvrami KineticsLimestone Gypsum ProcessProcess Optimization For DesulfurizationSeparation Mechanism DesignSulfur RemovalTemperature-dependent Reaction Kinetics
of the sulfur separation reaction is 34.84 kJ/mol. During the separation process, the pH of the solution gradually decreased due to the conversion of oxalic acid to sulfuric acid, so the liquid obtained after the sulfur separation of FGD gypsum can be recycled as industrial sulfuric acid. Nearly 1 mol of sulfuric acid can be obtained for every mole of oxalic acid consumption.
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