Simple process for separation and recycling of nylon 6 and polyurethane components from waste nylon 6/polyurethane debris

Abstract

The nylon 6 (PA6)/polyurethane (PU) debris produced during the sanding process would result in a serious resource waste and environmental hazard if disposed of inappropriately. Therefore, this study proposed a simple process for separating and recycling PA6 and PU components of PA6/PU debris. Results revealed that the instantaneous dissolution of PU in N,N-dimethylformamide was independent of temperature and time but related to the quantity of the solvent. Further investigation showed that 43.2% of waste PA6/PU debris was dissolved at room temperature, with pulp density of 10% and within 10 minutes, indicating that PA6 and PU could be quickly separated from the waste PA6/PU debris. In addition, proton nuclear magnetic resonance indicated that the dissolved PU could be recovered by selective precipitation-stripping using an equal amount of deionized water. Moreover, the chemical structure analysis disclosed that the PU in PA6/PU debris should be polyether PU synthesized by reacting with methylene diphenyl diisocyanate and polyether polyols. Besides, the stable chemical structure and thermal properties of separated samples observed from differential scanning calorimetry and thermogravimetry results confirmed that the recycling products could be reused as recycled plastic materials.