Concepedia

Identifying and controlling the acid site distributions in mordenite zeolite for dimethyl ether carbonylation reaction by means of selective ion-exchange

Shiping Liu, Hongchao Liu, Xiangang Ma, Yong Liu, Wenliang Zhu, Zhongmin Liu

Catalysis Science & Technology · 2020 · 37 citations · 32 references

DOI

Concepts

Abstract

The identification and regulation of acid site distributions in mordenite zeolites are accomplished by using tetramethylammonium ions to selectively exchange with the counter ions in 12-membered channels.

References

32

Selective Carbonylation of Dimethyl Ether to Methyl Acetate Catalyzed by Acidic Zeolites

Patricia Cheung, Aditya Bhan, Glenn J. Sunley et al. · Angewandte Chemie International Edition · 2006 · 401 citations

, , +12

Specificity of Sites within Eight-Membered Ring Zeolite Channels for Carbonylation of Methyls to Acetyls

Aditya Bhan, Ayman D. Allian, Glenn J. Sunley et al. · Journal of the American Chemical Society · 2007 · 360 citations

, , +14

Catalytic Consequences of Spatial Constraints and Acid Site Location for Monomolecular Alkane Activation on Zeolites

Rajamani Gounder, Enrique Iglesia · Journal of the American Chemical Society · 2009 · 323 citations

, , +18

Enzyme-like Specificity in Zeolites: A Unique Site Position in Mordenite for Selective Carbonylation of Methanol and Dimethyl Ether with CO

Mercedes Boronat, Cristina Martı́nez, David J. Law et al. · Journal of the American Chemical Society · 2008 · 318 citations

, , +16

A Link between Reactivity and Local Structure in Acid Catalysis on Zeolites

Aditya Bhan, Enrique Iglesia · Accounts of Chemical Research · 2008 · 295 citations

, , +13