Bioinspired Multifunctional Organic Transistors Based on Natural Chlorophyll/Organic Semiconductors

Abstract

Inspired by the photosynthesis process of natural plants, multifunctional transistors based on natural biomaterial chlorophyll and organic semiconductors (OSCs) are reported. Functions as photodetectors (PDs) and light-stimulated synaptic transistors (LSSTs) can be switched by gate voltage. As PDs, the devices exhibit ultrahigh photoresponsivity up to 2 × 10⁶ A W^-1 , detectivity of 6 × 10¹⁵ Jones, and I_photo /I_dark ratio of 2.7 × 10⁶ , which make them among the best reported organic PDs. As LSSTs, important synaptic functions similar to biological synapses are demonstrated, together with a dynamic learning and forgetting process and image-processing function. Significantly, benefiting from the ultrahigh photosensitivity of chlorophyll, the lowest operating voltage and energy consumption of the LSSTs can be 10^-5 V and 0.25 fJ, respectively. The devices also exhibit high flexibility and long-term air stability. This work provides a new guide for developing organic electronics based on natural biomaterials.