Ni(I)–Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO ₂ Insertion at Ni(I) Centers

Abstract

Although the catalytic carboxylation of unactivated alkyl electrophiles has reached remarkable levels of sophistication, the intermediacy of (phenanthroline)Ni(I)-alkyl species-complexes proposed in numerous Ni-catalyzed reductive cross-coupling reactions-has been subject to speculation. Herein we report the synthesis of such elusive (phenanthroline)Ni(I) species and their reactivity with CO₂, allowing us to address a long-standing question related to Ni-catalyzed carboxylation reactions.