Air‐Stable Fe₃O₄@SiO₂‐EDTA‐Ni(0) as an Efficient Recyclable Magnetic Nanocatalyst for Effective Suzuki‐Miyaura and Heck Cross‐Coupling via Aryl Sulfamates and Carbamates

Abstract

The synthesis of inexpensive and novel air‐stable Ni(0) nanoparticles immobilized on the EDTA‐modified Fe 3 O 4 @SiO 2 nanocatalyst was investigated in Suzuki‐Miyaura and Heck cross‐coupling reactions. This catalytic system displayed a greatly improved substrate scope for the carbon–carbon bond formations starting from a wide range of green and economical electrophiles aryl and heteroaryl carbamates and sulfamates via highly efficient method under mild, operationally simple reaction conditions. The synthesized heterogeneous catalyst was also fully characterized by FT‐IR, TEM, XRD, DLS, FE‐SEM, UV–Vis, EDX, XPS, TGA, NMR, VSM, ICP and elemental analysis techniques. The heterogeneous magnetic nanocatalyst can easily be recovered by an external magnetic field and reused for the next reactions for at least seven times with negligible leaching of catalyst and no substantial decrement in the activity. All these highlights have made the present protocol an interesting, simple and environmentally benign process with low catalyst loading and easy manipulations.