Banana Leaflike C-Doped MoS₂ Aerogels toward Excellent Microwave Absorption Performance

Abstract

We describe the design and manufacturing method of a lightweight C-doped MoS₂ aerogel with a special regular banana leaflike microstructure used for high-performance microwave absorbers. The aerogel precursor was first fabricated by a self-assembly process between alginate (Alg) and ammonium thiomolybdate (ATM), where Alg as a template was assembled with ATM into regular banana leaflike architectures along the ice growth direction during oriented freezing. After pyrolysis at 900 °C, the C-doped MoS₂ aerogels maintained low densities and porous hierarchal banana leaflike structures, where the banana leaves ranged in diameter from about 2 to 5 μm with the growth of small branches. Benefitting from these features, the C-doped MoS₂ aerogel possessed excellent microwave absorption performance in the frequency range of 2-18 GHz. The minimum reflection loss (RL) reached -43 dB at 5.4 GHz with a matching thickness of 4 mm, and the effective microwave absorption band (RL < -10 dB) reached 4 GHz (14-18 GHz) at a thickness of 1.5 mm. Our findings also provide strategies for designing MoS₂ aerogel nanostructures for electronic devices, catalysis, and other potential applications.