Concepedia

Synthesis, structure and reactivity of NO<sup>+</sup>, NO˙ and NO<sup>−</sup>pincer PCN-Rh complexes

Cecilia Mariel Gallego, Carina Gaviglio, Yehoshoa Ben‐David, David Milstein, Fabio Doctorovich, Juan Pellegrino

Dalton Transactions · 2020 · 12 citations · 44 references

DOI

Concepts

Abstract

Synthesis of a rhodium PCN pincer-type nitrosyl complex is described. Coordination to the metallic center by weakly coordinating anions was found, as well as a slight stabilization of higher oxidation states when compared to a PCP analogue.

References

44

Principles of structure, bonding, and reactivity for metal nitrosyl complexes

John H. Enemark, Robert D. Feltham · Coordination Chemistry Reviews · 1974 · 1.6K citations

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Safe Preparation and Purification of Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF<sub>24</sub>):  Reliable and Sensitive Analysis of Water in Solutions of Fluorinated Tetraarylborates

Neal A. Yakelis, Robert G. Bergman · Organometallics · 2005 · 320 citations · Full text

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The Reaction Mechanism of the Hydroamination of Alkenes Catalyzed by Gold(I)−Phosphine:  The Role of the Counterion and the N-Nucleophile Substituents in the Proton-Transfer Step

Gábor Kovács, Gregori Ujaque, Agustı́ Lledós · Journal of the American Chemical Society · 2008 · 201 citations

, , +14

Coordination chemistry of nitric oxide

Richard Eisenberg, Carol D. Meyer · Accounts of Chemical Research · 1975 · 183 citations

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A PCN Ligand System. Exclusive C−C Activation with Rhodium(I) and C−H Activation with Platinum(II)

Mark Gandelman, Arkadi Vigalok, Linda J. W. Shimon et al. · Organometallics · 1997 · 123 citations

, , +14