Concepedia

A highly active and robust iron quinquepyridine complex for photocatalytic CO<sub>2</sub> reduction in aqueous acetonitrile solution

Yanfei Qin, Lingjing Chen, Gui Chen, Zhenguo Guo, Lei Wang, Hongbo Fan, Marc Robert, Tai‐Chu Lau

Chemical Communications · 2020 · 32 citations · 42 references

DOI

Concepts

Abstract

[Fe(qnpy)(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup> is a highly efficient and robust catalyst for visible-light-driven reduction of CO<sub>2</sub> to CO, with a TON for CO of up to 14 095 and selectivity of 98% using Ru(phen)<sub>3</sub>Cl<sub>2</sub> as photosensitizer and BIH as sacrificial reductant.

References

42

Visible-light-driven methane formation from CO2 with a molecular iron catalyst

Heng Rao, Luciana C. Schmidt, Julien Bonin et al. · Nature · 2017 · 1K citations

, , +13

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO<sub>2</sub> Reduction

Hiroyuki Takeda, Claudio Cometto, Osamu Ishitani et al. · ACS Catalysis · 2016 · 683 citations

, , +17

Selective Photocatalytic CO<sub>2</sub> Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals

Moritz F. Kuehnel, Katherine L. Orchard, Kristian E. Dalle et al. · Journal of the American Chemical Society · 2017 · 529 citations

, , +17

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel <i>N</i>-Heterocyclic Carbene–Isoquinoline Complex

V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit et al. · Journal of the American Chemical Society · 2013 · 367 citations · Full text

, , +17

Highly Efficient and Selective Photocatalytic CO<sub>2</sub> Reduction by Iron and Cobalt Quaterpyridine Complexes

Zhenguo Guo, Siwei Cheng, Claudio Cometto et al. · Journal of the American Chemical Society · 2016 · 346 citations

, , +15