Science Advances · 2020 · 82 citations · 42 references
Natural SciencesMaterials SciencePhysicsCondensed Matter PhysicsMaterials PhysicsSolid State PhysicsAmorphous Electronic MaterialsAmorphous MaterialsAmorphous SolidsDisordered SystemsNanostructured Electronic MaterialsTwo-dimensional NanomaterialsAmorphous StructureElectronic Density Of StatesElectronic Structure Of Amorphous MaterialsElectronic TransportElectronic Transport In Disordered SystemsStructural DisorderTransport In Amorphous Materials
Disordered hyperuniformity (DHU) is a recently proposed new state of matter, which has been observed in a variety of classical and quantum many-body systems. DHU systems are characterized by vanishing infinite-wavelength normalized density fluctuations and are endowed with unique novel physical properties. Here, we report the discovery of disordered hyperuniformity in atomic-scale two-dimensional materials, i.e., amorphous silica composed of a single layer of atoms, based on spectral-density analysis of high-resolution transmission electron microscopy images. Moreover, we show via large-scale density functional theory calculations that DHU leads to almost complete closure of the electronic bandgap compared to the crystalline counterpart, making the material effectively a metal. This is in contrast to the conventional wisdom that disorder generally diminishes electronic transport and is due to the unique electron wave localization induced by the topological defects in the DHU state.
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Generalized Gradient Approximation Made Simple
John P. Perdew, Kieron Burke, Matthias Ernzerhof · Physical Review Letters · 1996 · 211.5K citations · Full text
Natural Sciences, Chemistry, Physics +16
Absence of Diffusion in Certain Random Lattices
P. W. Anderson · Physical Review · 1958 · 12.3K citations
Localization: theory and experiment
B. Krämer, A. MacKinnon · Reports on Progress in Physics · 1993 · 1.9K citations