Aerosol–photolysis interaction reduces particulate matter during wintertime haze events

Abstract

Aerosol-radiation interaction (ARI) plays a significant role in the accumulation of fine particulate matter (PM_2.5) by stabilizing the planetary boundary layer and thus deteriorating air quality during haze events. However, modification of photolysis by aerosol scattering or absorbing solar radiation (aerosol-photolysis interaction or API) alters the atmospheric oxidizing capacity, decreases the rate of secondary aerosol formation, and ultimately alleviates the ARI effect on PM_2.5 pollution. Therefore, the synergetic effect of both ARI and API can either aggravate or even mitigate PM_2.5 pollution. To test the effect, a fully coupled Weather Research and Forecasting (WRF)-Chem model has been used to simulate a heavy haze episode in North China Plain. Our results show that ARI contributes to a 7.8% increase in near-surface PM_2.5 However, API suppresses secondary aerosol formation, and the combination of ARI and API results in only 4.8% net increase of PM_2.5 Additionally, API increases the solar radiation reaching the surface and perturbs aerosol nucleation and activation to form cloud condensation nuclei, influencing aerosol-cloud interaction. The results suggest that API reduces PM_2.5 pollution during haze events, but adds uncertainties in climate prediction.