IOP Conference Series Materials Science and Engineering · 2019 · 21 citations · 11 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistrySolid-state ChemistrySurface ChemistryCatalyst PreparationMetal Framework FabricationGas StorageMetal-organic Framework SynthesisMetal-organic FrameworksSolvothermal SynthesisSpecific Surface AreaSurface AreaSurface Area CharacterizationX-ray Diffraction Analysis
Abstract This research demonstrates the preparation of a metal-organic framework (MOF-199) using the solvothermal method. The solvothermal conditions for synthesis and activation were investigated by changing the synthesis time (24 - 48 h), the solvothermal temperatures (85 and 100 °C), and the effect of the ethanol: water solvent ratio (within the solvents range from 1:1 to 1:2 ratios). All synthesized samples were characterized using of x-ray diffraction (XRD), scanning electron microscopy (SEM) and specific surface area (BET). The prepared MOF-199 at the optimal conditions (100 °C for 48 h, 1:1 of the ethanol: water) has up to 5518 m 2 /g m 2 /g surface area (BET), 0.693 cm 3 g −1 specific volume, a 11.8 Å porous size, and 103 crystallinity. All MOF-199 samples were activated for 21 h at 60 °C.
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Metal–organic frameworks—prospective industrial applications
U. Müeller, Markus M. Schubert, F. Teich et al. · Journal of Materials Chemistry · 2005 · 2.3K citations
Natural Sciences, Materials Engineering, Materials Science +17