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A thiophene bridged naphthalimide–porphyrin complex with enhanced activity and stability in photocatalytic H<sub>2</sub> evolution
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Citations
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References
2020
Year
Analogous Porphyrin ZntEngineeringInorganic PhotochemistryExcitation Energy TransferOrganic ChemistryChemistryChemical EngineeringPhotoredox ProcessEnhanced ActivityPhotocatalysisBiophysicsElectron Rich CoplanarInorganic ChemistryPhotochemistryMechanistic PhotochemistryNaphthalimide–porphyrin ComplexCatalysisMolecular ChemistrySupramolecular Chemistry
More efficient intramolecular energy transfer in the naphthalimide–porphyrin complex, ZnT(p-NI)TP, is accomplished by an electron rich coplanar thiophene π-linkage compared to the analogous porphyrin ZnT(p-NI)PP bearing a less coplanar phenylene π-linker.
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