Construction of Bimetallic Selenides Encapsulated in Nitrogen/Sulfur Co‐Doped Hollow Carbon Nanospheres for High‐Performance Sodium/Potassium‐Ion Half/Full Batteries

Abstract

Metallic selenides have been widely investigated as promising electrode materials for metal-ion batteries based on their relatively high theoretical capacity. However, rapid capacity decay and structural collapse resulting from the larger-sized Na⁺ /K⁺ greatly hamper their application. Herein, a bimetallic selenide (MoSe₂ /CoSe₂ ) encapsulated in nitrogen, sulfur-codoped hollow carbon nanospheres interconnected reduced graphene oxide nanosheets (rGO@MCSe) are successfully designed as advanced anode materials for Na/K-ion batteries. As expected, the significant pseudocapacitive charge storage behavior substantially contributes to superior rate capability. Specifically, it achieves a high reversible specific capacity of 311 mAh g^-1 at 10 A g^-1 in NIBs and 310 mAh g^-1 at 5 A g^-1 in KIBs. A combination of ex situ X-ray diffraction, Raman spectroscopy, and transmission electron microscopy tests reveals the phase transition of rGO@MCSe in NIBs/KIBs. Unexpectedly, they show quite different Na⁺ /K⁺ insertion/extraction reaction mechanisms for both cells, maybe due to more sluggish K⁺ diffusion kinetics than that of Na⁺ . More significantly, it shows excellent energy storage properties in Na/K-ion full cells when coupled with Na₃ V₂ (PO₄ )₂ O₂ F and PTCDA@450 °C cathodes. This work offers an advanced electrode construction guidance for the development of high-performance energy storage devices.