Tetraphenylethylene(TPE)-Containing Metal–Organic Nanobelt and Its Turn-on Fluorescence for Sulfide (S^2–)

Abstract

A metal-organic supramolecular nanobelt was synthesized by quantitative self-assembling terpyridine-functionized tetraphenylethylene (TPE) and Cd²⁺, which only showed a weak emission both in solution or aggregated state. Nevertheless, nanobelt complex could be transferred to a fluorescence turn-on sensor to S^2- by taking advantage of the structural transformation from nanobelt to its fluorescent ligand.