The Synthesis of a Quasi-One-Dimensional Iron-Based Telluride with Antiferromagnetic Chains and a Spin Glass State

Abstract

The report on the superconductivity of the two-legged spin ladders BaFe₂S₃ and BaFe₂Se₃ has established 123-type iron chalcogenides as a novel subgroup in the iron-based superconductor family and has stimulated the continuous exploration of other iron-based materials with new structures and potentially novel properties. In this paper, we report the systematic study of a new quasi-one-dimensional (1D) iron-based compound, Ba₉Fe₃Te₁₅, including its synthesis and magnetic properties. The high-pressure synthesized Ba₉Fe₃Te₁₅ crystallized in a hexagonal structure that mainly consisted of face-sharing FeTe₆ octahedral chains running along the <i>c</i> axis, with a lattice constant of <i>a</i> = 10.23668 Å; this led to weak interchain coupling and an enhanced one-dimensionality. The systematic static and dynamic magnetic properties were comprehensively studied experimentally. The dc magnetic susceptibility showed typical 1D antiferromagnetic characteristics, with a <i>T</i>_max at 190 K followed by a spin glass (SG) state with freezing at <i>T</i>_f ≈ 6.0 K, which were also unambiguously proved by ac susceptibility measurements. Additionally, X-ray magnetic circular dichroism (XMCD) experiments revealed an unexpected orbital moment for Fe²⁺, i.e., 0.84 μ_B per Fe in Ba₉Fe₃Te₁₅. The transport property is electrically insulating, with a thermal activation gap of 0.32 eV. These features mark Ba₉Fe₃Te₁₅ as an alternative type of iron-based compound, providing a diverse candidate for high-pressure studies in order to pursue some emerging physics.