Glyoxylic Sulfuric Anhydride from the Gas-Phase Reaction between Glyoxylic Acid and SO₃: A Potential Nucleation Precursor

Abstract

Oxocarboxylic acids, one of the most important organic species, are detected in aerosols in various environments. Recent studies suggest that the gas-phase reactions between carboxylic acids and SO₃ could form carboxylic sulfuric anhydrides, which might participate in nucleation. Here, glyoxylic acid (<b>GA</b>), the most abundant oxocarboxylic acid in the atmosphere, has been selected as an example to study the reactions between oxocarboxylic acids and SO₃ and the nucleation potentials of products. The reaction between <b>GA</b> and SO₃ that generates glyoxylic sulfuric anhydride (<b>GSA</b>) and the hydrolysis of <b>GSA</b> are investigated using computational methods. The results show that the reaction is almost barrierless, and <b>GSA</b> is stable against water. Additionally, the clusters of <b>GSA</b> and common nucleation species (sulfuric acid and ammonia) are more stable than the analogous clusters of <b>GA</b>, because they have more hydrogen bonds and proton transfers. It suggests that <b>GA</b> tends to transfer itself to a much better nucleation precursor, <b>GSA</b>, through a reaction with SO₃, and <b>GSA</b> can drive nucleation and contribute to new particle formation (NPF). This mechanism might be general for all oxocarboxylic acids and could help to deeply understand the roles of oxocarboxylic acids in NPF.