Concepedia

Single-step benzene hydroxylation by cobalt(<scp>ii</scp>) catalysts <i>via</i> a cobalt(<scp>iii</scp>)-hydroperoxo intermediate

Karunanithi Anandababu, Sethuraman Muthuramalingam, Marappan Velusamy, Ramasamy Mayilmurugan

Catalysis Science & Technology · 2020 · 31 citations · 38 references

DOI

Concepts

Abstract

Cobalt(<sc>ii</sc>) complexes reported as efficient and selective catalysts for single-step phenol formation from benzene using H<sub>2</sub>O<sub>2</sub>. The catalysis proceeds likely <italic>via</italic> cobalt(<sc>iii</sc>)-hydroperoxo species.

References

38

Synthesis, structure, and spectroscopic properties of copper(<scp>II</scp>) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper(<scp>II</scp>) perchlorate

Anthony W. Addison, T. Nageswara Rao, J. Reedijk et al. · Journal of the Chemical Society Dalton Transactions · 1984 · 9.3K citations

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Direct Hydroxylation of Benzene to Phenol Using Hydrogen Peroxide Catalyzed by Nickel Complexes Supported by Pyridylalkylamine Ligands

Yuma Morimoto, Shuji Bunno, Nobutaka Fujieda et al. · Journal of the American Chemical Society · 2015 · 203 citations

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Direct Oxygenation of Benzene to Phenol Using Quinolinium Ions as Homogeneous Photocatalysts

Kei Ohkubo, Takaki Kobayashi, Shunichi Fukuzumi · Angewandte Chemie International Edition · 2011 · 198 citations · Full text

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Direct Oxidation of Benzene to Phenol with Hydrogen Peroxide over a Modified Titanium Silicalite

Luigi Balducci, Daniele Bianchi, Rossella Bortolo et al. · Angewandte Chemie International Edition · 2003 · 196 citations

, , +17

Remarkably High Reactivity of Pd(OAc)<sub>2</sub>/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes

Marion H. Emmert, Amanda K. Cook, Yushu J. Xie et al. · Angewandte Chemie International Edition · 2011 · 174 citations · Full text

, , +12