Fluorescence to multi-colored phosphorescence interconversion of a novel, asterisk-shaped luminogen <i>via</i> multiple external stimuli

Abstract

We designed and characterized an asterisk-shaped luminogen, hexakis(pyridin-4-ylthio)benzene (HPTB). Via external stimuli such as CH₃OH, H⁺, and Ag⁺, HPTB's luminogenic character transitioned from blue fluorescence to green, yellow, and orange phosphorescence. Results showed that this interconversion was a reversible process that was also reproducible in liquid and in the solid state.