Nanostructured potassium–organic framework as an effective anode for potassium-ion batteries with a long cycle life

Abstract

Finding new organic materials to address several issues (e.g. capacity, stability, and cycle life) in organic potassium-ion batteries (OPIBs) is very important and highly desirable. Here, to directly investigate the redox reaction of organic pyridine dicarboxylate in OPIBs and to avoid the interference from the redox-active metal ions, a non-redox-metal potassium metal-organic framework (K-MOF), [C₇H₃KNO₄]_n, based on pyridine-2,6-dicarboxylic acid (H₂PDA), has been successfully synthesized and applied as a promising organic anode for long-cycle life PIBs. The crystal structure of [C₇H₃KNO₄]_n was confirmed by single-crystal X-ray diffraction analysis and FT-IR spectra. Moreover, the potassium-storage mechanism of organic pyridine dicarboxylate ligand was revealed by ex situ FT-IR/XRD characterization and theoretical calculations. The as-synthesized K-MOF resulted in a unique and reversible three-step redox reaction, exhibited superior electrochemical performance with the aid of N-K/O-K coordination bonds, and showed a high average specific capacity of 115 mA h g^-1 at 100 mA g^-1 for 300 cycles with the capacity retention of 92%.