Boosting Multiple Interfaces by Co-Doped Graphene Quantum Dots for High Efficiency and Durability Perovskite Solar Cells

Abstract

Organic-inorganic hybrid perovskite solar cells (PSCs), as the most rapidly developing next-generation thin-film photovoltaic technology, have attracted extensive research interest, yet their efficiency, scalability, and durability remain challenging. α-Fe₂O₃ could be used as an electron transporting layer (ETL) of planar PSCs, which exhibits a much higher humidity and UV light-stability compared to TiO₂-based planar PSCs. However, the photovoltaic conversion efficiency (PCE) of the Fe₂O₃-based device was still below 15% because of poor interface contact between α-Fe₂O₃ and perovskite and poor crystal quality of perovskites. In this work, we have engineered the interfaces throughout the entire solar cell <i>via</i> incorporating N, S co-doped graphene quantum dots (NSGQDs). The NSGQDs played remarkable multifunctional roles: (i) facilitated the perovskite crystal growth; (ii) eased charge extraction at both anode and cathode interfaces; and (iii) induced the defect passivation and suppressed the charge recombination. When assembled with a α-Fe₂O₃ ETL, the planar PSCs exhibited a significantly increased efficiency from 14 to 19.2%, with concomitant reductions in hysteresis, which created a new record of the PCE for Fe₂O₃-based PSCs to date. In addition, PSCs with the entire device interfacial engineering showed an obviously improved durability, including prominent humidity, UV light, and thermal stabilities. Our interfacial engineering methodology <i>via</i> graphene quantum dots represents a versatile and effective way for building high efficiency as well as durable PSCs.