European Journal of Organic Chemistry · 2020 · 31 citations · 48 references
Natural SciencesChemical EngineeringChemistryCatalysisElectrochemistryOrganic ChemistryCatalytic MechanismsElectrochemical CellsElectrochemical SynthesisHeterocycle SynthesisHeterocyclic ChemistryRedox CatalysisElectrocatalytic ReactorsElectrochemical Coupling ReactionsElectrochemical ReactionsIndirect ElectrolysisMediator-based Electrosynthesis
Recognized as gentler and more environmentally friendly compared to conventional methods, catalytic electrochemical reactions are a powerful tool for constructing heterocycles. Of special interest is indirect electrolysis, where the use of a redox mediator provides an additional means of reaction control, thus avoiding over‐oxidation and facilitating improved selectivity. This minireview describes recent advances in catalytic electrochemical reactions for synthesizing N , O ‐heterocycles that appeared from 2018 until September 2019.
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Electrochemical Difluoromethylarylation of Alkynes
Peng Xiong, He‐Huan Xu, Hai‐Chao Xu et al. · Journal of the American Chemical Society · 2018 · 274 citations