Bright Blue Light Emission of Ni²⁺ Ion-Doped CsPbCl<i>_x</i>Br_3–<i>x</i> Perovskite Quantum Dots Enabling Efficient Light-Emitting Devices

Abstract

In recent years, significant advances have been achieved in the red and green perovskite quantum dot (PQD)-based light-emitting diodes (LEDs). However, the performances of the blue perovskite LEDs are still seriously lagging behind that of the green and red counterparts. Herein, we successfully developed Ni²⁺ ion-doped CsPbCl<i>_x</i>Br_3-<i>x</i> PQDs through the room-temperature supersaturated recrystallization synthetic approach. We simultaneously realized the doping of various concentrations of Ni²⁺ cations and modulated the Cl/Br element ratios by introducing different amounts of NiCl₂ solution in the reaction medium. Using the synthetic method, not only the emission wavelength from 508 to 432 nm of Ni²⁺ ion-doped CsPbCl<i>_x</i>Br_3-<i>x</i> QDs was facially adjusted, but also the photoluminescence quantum yield (PLQY) of PQDs was greatly improved due to efficient removal of the defects of the PQDs. Thus, the blue emission at 470 nm with PLQY of 89% was achieved in 2.5% Ni²⁺ ion-doped CsPbCl_0.99Br_2.01 QDs, which increased nearly three times over that of undoped CsPbClBr₂ QDs and was the highest for the CsPbX₃ PQDs with blue emission, fulfilling the National Television System Committee standards. Benefiting from the highly luminous Ni²⁺ ion-doped PQDs, the blue-emitting LED at 470 nm was obtained, exhibiting an external quantum efficiency of 2.4% and a maximum luminance of 612 cd/m², which surpassed the best performance reported previously for the corresponding blue-emitting PQD-based LED.