Nature Communications · 2020 · 417 citations · 36 references
Natural SciencesMaterials EngineeringMaterials ScienceCrystal StructureMetallurgyPhase TransformationsAlloysDeformation MechanismsMetalsMetastable PhasesStacking FaultsStrain HardeningDislocation MechanismsFace-centered Cubic LatticeFace-centered Cubic StructureHigh-entropy AlloysMetastable Alloy PhasesPlastic Deformation BehaviorStacking Fault NucleationStrain Hardening Rate
Abstract Strategies involving metastable phases have been the basis of the design of numerous alloys, yet research on metastable high-entropy alloys is still in its infancy. In dual-phase high-entropy alloys, the combination of local chemical environments and loading-induced crystal structure changes suggests a relationship between deformation mechanisms and chemical atomic distribution, which we examine in here in a Cantor-like Cr 20 Mn 6 Fe 34 Co 34 Ni 6 alloy, comprising both face-centered cubic ( fcc ) and hexagonal closed packed ( hcp ) phases. We observe that partial dislocation activities result in stable three-dimensional stacking-fault networks. Additionally, the fraction of the stronger hcp phase progressively increases during plastic deformation by forming at the stacking-fault network boundaries in the fcc phase, serving as the major source of strain hardening. In this context, variations in local chemical composition promote a high density of Lomer-Cottrell locks, which facilitate the construction of the stacking-fault networks to provide nucleation sites for the hcp phase transformation.
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