Improved performance of dye-sensitized solar cells upon sintering of a PEDOT cathode at various temperatures

Abstract

Poly(3,4-ethylenedioxythiophene) (PEDOT) thin films have attracted considerable attention as cathodes for dye-sensitized solar cells (DSSCs) due to their air-stable, light-weight and conductive nature. To demonstrate their thermal stability as cathodes, PEDOT thin films coated <i>via</i> electrochemical polymerization on fluorine doped tin oxide (FTO) plates were sintered at different temperatures (50, 100, 150, 200, and 300 °C) for 1 h and a comparison was made with the as-prepared PEDOT thin films. We observed a negative temperature coefficient effect up to 200 °C along with lower surface roughness upon increasing the sintering temperature. Dye solar cells were fabricated using PEDOT thin films (sintered at different temperatures) and as-prepared PEDOT cathodes, and their respective performances were studied. The results showed increased efficiency with the increase in sintering temperatures of the cathode up to 200 °C (<i>η</i> = 4.33%) under the present experimental conditions. Cathodes sintered at 300 °C had poor electrochemical behavior and <i>J</i>-<i>V</i> performance, which may be due to polymer degradation.