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Is It Possible To Prepare a Heterometal Anderson–Evans Type Anion?

DOI

12

Citations

26

References

2020

Year

Anna A. Mukhacheva, Victoria V. Volchek, Vadim V. Yanshole, Nikolay B. Kompankov, Artem L. Gushchin, Enrico Benassi, Pavel A. Abramov⧫, Maxim N. Sokolov⧫
Inorganic Chemistry

Abstract

Reaction of [SbW<sub>9</sub>O<sub>33</sub>]<sup>9-</sup> with [Pt(H<sub>2</sub>O)<sub>2</sub>(OH)<sub>4</sub>] results in the first example of the mixed addenda Anderson-Evans type Pt<sup>IV</sup>{Sb<sup>V</sup>(OH)<sub>2</sub>}W<sup>VI</sup><sub>5</sub>O<sub>22</sub>]<sup>7-</sup> anion, isolated and characterized as K<sub>6</sub>Na<sub>2</sub>[Pt{Sb(OH)<sub>2</sub>}W<sub>5</sub>O<sub>22</sub>](NO<sub>3</sub>)<sub>0.1</sub>(OH)<sub>0.9̇</sub>11H<sub>2</sub>O (<b>1</b>).

References

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