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Lewis pair catalyzed highly selective polymerization for the one-step synthesis of A<sub>z</sub>C<sub>y</sub>(AB)<sub>x</sub>C<sub>y</sub>A<sub>z</sub> pentablock terpolymers
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Citations
31
References
2020
Year
EngineeringOrganic ChemistryLewis PairChemistryPolymersChemical EngineeringFeed RatioOne-step SynthesisKinetic ControlPolymer ChemistryOne-step ProcedureCatalysisSynthesis MethodPolymer ScienceSelective PolymerizationPolymerization KineticsPolymer ReactionSynthetic ChemistryPolymer Synthesis
A Et<sub>3</sub>B/DBU pair with a 2/1 feed ratio allowed for the chemoselective control and kinetic control over terpolymerization of epoxides, anhydrides and <italic>rac</italic>-lactides, affording unique A<sub>z</sub>C<sub>y</sub>(AB)<sub>x</sub>C<sub>y</sub>A<sub>z</sub> pentablock terpolymers in a one-step procedure.
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