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A Highly Asymmetric Gold(III) η<sup>3</sup>‐Allyl Complex

23

Citations

17

References

2019

Year

Abstract

A highly asymmetric Au<sup>III</sup> η<sup>3</sup> -allyl complex has been generated by treating Au(η<sup>1</sup> -allyl)Br(tpy) (tpy=2-(p-tolyl)pyridine) with AgNTf<sub>2</sub> . The resulting η<sup>3</sup> -allyl complex has been characterized by NMR spectroscopy and X-ray crystallography. DFT calculations and variable temperature <sup>1</sup> H NMR suggest that the allyl ligand is highly fluxional.

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2017

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1966

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2012

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