Concepedia

Rhodium-catalyzed ene-cycloisomerization of allylic-sulfide-tethered alkylidenecyclopropanes: DFT analysis of origins of regio- and diastereo-selectivities

Ting Wang, Shuting Lv, Xianming Guo, Zhanpeng Li, Juan Li

Organic Chemistry Frontiers · 2020 · 10 citations · 70 references

DOI

Concepts

Abstract

A unconventional reaction mechanism can be responsible for the regio- and diastereo-selectivities of rhodium-catalyzed ene-cycloisomerization of allylic-sulfide-tethered alkylidenecyclopropanes.

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