Magnetic recyclable CoFe₂O₄@PPy prepared by <i>in situ</i> Fenton oxidization polymerization with advanced photo-Fenton performance

Abstract

Here we present a magnetic recyclable photo-Fenton catalyst CoFe₂O₄@PPy with uniform morphology and excellent dispersibility prepared <i>via</i> simple <i>in situ</i> Fenton oxidization polymerization. The CoFe₂O₄ core provides good magnetic recyclability for the catalysts as well as the ion source for catalyzed decomposition of H₂O₂ in PPy coating. The optimal catalytic effect can be obtained by adjusting the ratio of CoFe₂O₄ and PPy. Methylene blue, Methyl orange and Rhodamine B (RhB) employed as model pollutants certificated that the catalyst exhibits a wide range of photodegradability. The decoloration rates reach nearly 100% in the photodegradation of 10 mg L^-1 RhB after 2 h visible-light irradiation and only low toxicity small molecules are detected by LC-MS. Moreover, the catalytic activity remains after 5 cycles with decoloration rates up to 90%. The degradation measurement in the presence of scavengers of reactive species reveals that the positive holes (h⁺) and hydroxyl radical (·OH) are the main reactive oxygen species in the CoFe₂O₄@PPy system. The performance enhancement may be attributed to the combination of improved Fenton activity by coordinated Fe²⁺ and PPy redox pairs and photo-catalytic activity by broaden adsorption and photo-generated charge separation.