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Ti<sub>4</sub>(embonate)<sub>6</sub> Cage-Ligand Strategy on the Construction of Metal–Organic Frameworks with High Stability and Gas Sorption Properties

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Citations

23

References

2020

Year

Abstract

Herein we report an efficient strategy to construct cage-based metal-organic frameworks (MOFs) via the assembly of Ti<sub>4</sub>L<sub>6</sub> (L = embonate) cages and N-contained ligands with Mn<sup>2+</sup> and Zn<sup>2+</sup> ions, respectively, and two Ti<sub>4</sub>L<sub>6</sub>-cage-based MOFs (<b>PTC-219</b> and <b>PTC-220</b>) with high stability and gas sorption properties have been generated through two-step reactions, respectively.

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