Concepedia

Hydroboration of internal alkynes catalyzed by FeH(CO)(NO)(PPh<sub>3</sub>)<sub>2</sub>: a case of boron-source controlled regioselectivity

Fabian Rami, Franziska Bächtle, Bernd Plietker

Catalysis Science & Technology · 2020 · 26 citations · 48 references

DOI

Concepts

Abstract

The Fe–H complex FeH(CO)(NO)(Ph<sub>3</sub>P)<sub>2</sub> catalyzes the stereoselective, regiodivergent hydroboration of internal alkynes using either pinacolborane (HBpin) or bis(pinacolato)diboron (B<sub>2</sub>pin<sub>2</sub>) as a boron source.

References

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