Concepedia

Reactions of carbene-stabilized borenium cations

J.W.Y. Lam, Levy L. Cao, Jeffrey M. Farrell, Douglas W. Stephan

Dalton Transactions · 2020 · 11 citations · 29 references

DOI

Concepts

Abstract

A borenium cation containing BH bond is shown to react with olefins, alkynes vinyl-pyridine and phosphinoalkene. Related reactivity of C3-borenium cations with the FLP, P<italic>t</italic>Bu<sub>3</sub>/B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> is shown to give the zwitterionic borenium-borate species.

References

29

A consistent and accurate<i>ab initio</i>parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

Stefan Grimme, Jens Antony, Stephan Ehrlich et al. · The Journal of Chemical Physics · 2010 · 56.9K citations

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The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals

Yan Zhao, Donald G. Truhlar · Theoretical Chemistry Accounts · 2007 · 30K citations · Full text

, , +17

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

Florian Weigend, Reinhart Ahlrichs · Physical Chemistry Chemical Physics · 2005 · 29.9K citations

, , +15

Natural population analysis

Alan E. Reed, Robert B. Weinstock, Frank Weinhold · The Journal of Chemical Physics · 1985 · 9.8K citations

, , +4

Accurate Coulomb-fitting basis sets for H to Rn

Florian Weigend · Physical Chemistry Chemical Physics · 2006 · 8.8K citations

, , +12