Water, a Green Solvent for Fabrication of High-Quality CsPbBr₃ Films for Efficient Solar Cells

Abstract

Water has been labeled as a devil in fabrication and stability of perovskite solar cells. The inherent cognition impels researchers to prepare perovskite films in water-controlled conditions. Herein, water is used as a green solvent to prepare CsPbBr3 films through a two-step spin-coating method. Due to the high solubility of CsBr but low solubility of PbBr2 in water, it provides a possibility to deposit CsBr onto PbBr2 from water solution without destroying the film. Here, high-quality CsPbBr3 films are fabricated by spin-coating concentrated CsBr/H2O solution onto the PbBr2 film followed by annealing. As a result, the solar cells basing on a configuration of FTO/TiO2/CsPbBr3/Carbon exhibit a power conversion efficiency of 6.12%. This work provides a simple and easy way to prepare high-quality CsPbBr3 films for efficient solar cells. It makes a solid step toward reducing the solvent toxicity in the fabrication process of perovskite solar cells. It also breaks the forbidden zone for fabricating perovskite films from water and updates the inherent understanding of water in the research study of perovskite solar cells.