ACS Macro Letters · 2020 · 33 citations · 38 references
Natural SciencesChemical EngineeringChemistryCatalysisPolymer ChemistryPolymer EngineeringCatalytic MaterialsCatalytic MechanismsOptical PolymersPhotocatalysisPhotochemical SynthesisPhotochemistryEnantioselective SynthesisHeterogeneous PhotocatalysisMetal-organic Framework PhotocatalystsPhotocatalyst PreparationPhotocatalytic MaterialsPorous PolymersSuzuki - Miyaura CouplingVisible-light Photocatalysis
cores are prepared via one-pot Suzuki-Miyaura coupling reactions. Both Ru-POPs are thermally stable at up to 340 °C in air and do not dissolve in all solvents tested. One of the POPs has been revealed to be highly effective and reusable as a heterogeneous photocatalyst for visible light-driven enantioselective alkylation of aldehydes. After 10 cycles, the catalyst still maintains the enantioselectivity, while the activity just decreases slightly.
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