Fullerenes Nanotubes and Carbon Nanostructures · 2019 · 14 citations · 40 references
Natural SciencesMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologyThin FilmsCarbon NanomaterialsSurface PhysicsThermodynamics Of NanomaterialsThermoelectric MaterialsThin Film Electrical PropertiesThin Film Thermal PropertiesCarbon-based NanomaterialsCarbon-based NanostructuresField EmissionHeat GenerationSilicon WafersSurface PotentialThermoelectric Thin FilmsThin Film Thermoelectrics
Thin carbon films consisting of separate nanometer-scale sp2 carbon islands with smooth vacuum boundary deposited on Si wafers were found to be capable of low-field electron emission – starting from macroscopic field magnitudes as low as ∼1 V/µm. For such films, we suggest a novel model of emission facilitation by thermoelectric field associated with heat generation concentrated in nanosized areas. Quantitative estimates performed on the basis of this hypothesis for typical experimental conditions gave estimates for local thermoelectric field magnitude and lateral non-uniformity of surface potential as high as ∼100 V/μm and a few Volts, respectively. Thus, the suggested model explains the low-field emission capability of smooth-surface nanocarbon films observed in many previous experiments.
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David G. Cahill, W. K. Ford, Kenneth E. Goodson et al. · Journal of Applied Physics · 2003 · 3.2K citations · Full text
Arthur J. Nozik · Annual Review of Physical Chemistry · 2001 · 768 citations