Molecule Isomerism Modulates the Diradical Properties of Stable Singlet Diradicaloids

Joshua E. Barker, Justin J. Dressler, Abel Cárdenas Valdivia, Ryohei Kishi, Eric T. Strand, Lev N. Zakharov, Samantha N. MacMillan, Carlos J. Gómez‐García, Masayoshi Nakano, Juan Casado,

Journal of the American Chemical Society · 2019 · 101 citations · 38 references

Concepts

Abstract

derivatives based on structural, spectroscopic, theoretical, and magnetic measurements, showing that these systems are stable open-shell singlet diradicaloids that only access their triplet state at elevated temperatures.

References

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