Organic & Biomolecular Chemistry · 2019 · 10 citations · 35 references
Natural SciencesBiochemistryChemistryMineralogyProtein BiochemistryMineral TransformationPeptide ChemistryProtein PhosphorylationSilicate MineralogySilicate MineralsDilution ControlHigh-dilution SynthesisProtein MineralizationSilicate ChemistrySilicate Mineral Chemistry
. As opposed to this, unphosphorylated poly-cationic peptides or LCPA require concentrations above 1 mM for silicification. Hyperphosphorylated peptides showed a linear dependence between the amount of dissolved peptides and the amount of precipitated silica in the concentration range below 1 mM. Under mildly acidic conditions and short precipitation times, the concentration of the added LCPA determined the size of the silica spheres.
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Self-Assembly of Highly Phosphorylated Silaffins and Their Function in Biosilica Morphogenesis
Nils Kröger, Sonja Lorenz, Eike Brunner et al. · Science · 2002 · 800 citations