Advanced Synthesis & Catalysis · 2019 · 93 citations · 23 references
Natural SciencesChemistryMedicinal ChemistryDrug DiscoveryOrganic ChemistrySynthetic Medicinal ChemistryPhotochemical SynthesisPhotochemistryCarbazole ChemistryPyrazole ChemistryTriazole Chemistry
Abstract Blue light irradiation of aryldiazoacetates leads to the formation of free carbenes, which can react with carbazoles, pyrazoles and 1,2,3‐triazoles to afford the corresponding N−H inserted products. These reactions are performed under air and at room temperature, allowing the mild preparation of a variety of motifs found in biologically relevant targets. magnified image
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Blue light-promoted photolysis of aryldiazoacetates
Igor D. Jurberg, Huw M. L. Davies · Chemical Science · 2018 · 395 citations · Full text
Blue‐Light‐Induced Carbene‐Transfer Reactions of Diazoalkanes
Renè Hommelsheim, Yujing Guo, Zhen Yang et al. · Angewandte Chemie International Edition · 2018 · 275 citations