Blue Light‐Promoted N−H Insertion of Carbazoles, Pyrazoles and 1,2,3‐Triazoles into Aryldiazoacetates

Mateus L. Stivanin, Alessandra A. G. Fernandes, Amanda F. da Silva, Celso Y. Okada, Igor D. Jurberg

Advanced Synthesis & Catalysis · 2019 · 93 citations · 23 references

Concepts

Abstract

Abstract Blue light irradiation of aryldiazoacetates leads to the formation of free carbenes, which can react with carbazoles, pyrazoles and 1,2,3‐triazoles to afford the corresponding N−H inserted products. These reactions are performed under air and at room temperature, allowing the mild preparation of a variety of motifs found in biologically relevant targets. magnified image

References

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