Publication | Open Access
How coverage influences thermodynamic and kinetic isotope effects for H<sub>2</sub>/D<sub>2</sub> dissociative adsorption on transition metals
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Citations
76
References
2019
Year
EngineeringOxygen IsotopeChemistryKinetic Isotope EffectsEarth ScienceChemical EngineeringIsotope EffectsBiogeochemistryHydrogen Isotope EffectsChemisorptionPhysical ChemistryAdsorptionHydrogenSurface ChemistryTransition MetalsIsotope GeochemistryStable Isotope ProbingGeochemistryObserved Isotope EffectsChemical KineticsSurface Reactivity
Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.
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