Concepedia

Monoaurated <i>vs.</i> diaurated intermediates: causality or independence?

Mariarosa Anania, Lucie Jašíková, Jan Zelenka, Elena Shcherbachenko, Juraj Jašík, Jana Roithová

Chemical Science · 2019 · 14 citations · 50 references

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Concepts

Abstract

Reaction kinetics and detected α-gold ketone intermediates reveal that gold-mediated hydration of alkynes does not rely on dual activation.

References

50

Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation

John P. Perdew, J. A. Chevary, S. H. Vosko et al. · Physical review. B, Condensed matter · 1992 · 22K citations

, , +16

Generalized gradient approximation for the exchange-correlation hole of a many-electron system

John P. Perdew, Kieron Burke, Yue Wang · Physical review. B, Condensed matter · 1996 · 6.8K citations

, , +10

Harmonic Vibrational Frequencies:  An Evaluation of Hartree−Fock, Møller−Plesset, Quadratic Configuration Interaction, Density Functional Theory, and Semiempirical Scale Factors

Anthony P. Scott, Leo Radom · The Journal of Physical Chemistry · 1996 · 6.7K citations

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Exchange functionals with improved long-range behavior and adiabatic connection methods without adjustable parameters: The mPW and mPW1PW models

Carlo Adamo, Vincenzo Barone · The Journal of Chemical Physics · 1998 · 3.4K citations

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Merging Visible Light Photoredox and Gold Catalysis

Matthew N. Hopkinson, Adrián Tlahuext-Aca, Frank Glorius · Accounts of Chemical Research · 2016 · 660 citations

, , +16