Concepedia

Preventing Pd–NHC bond cleavage and switching from nano-scale to molecular catalytic systems: amines and temperature as catalyst activators

Oleg V. Khazipov, Dmitry V. Pasyukov, Andrey Yu. Chernenko, Alexander V. Astakhov, Victor M. Chernyshev, Valentine P. Ananikov

Catalysis Science & Technology · 2019 · 26 citations · 79 references

DOI

Concepts

Abstract

Heating Pd/NHC complexes with aliphatic amines induces Pd–NHC bond cleavage, while treating the complexes with primary or secondary aliphatic amines in the presence of strong bases promotes the activation of molecular Pd/NHC catalysis.

References

79

A short history of<i>SHELX</i>

George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 2007 · 87.4K citations · Full text

, , +16

<i>SHELXT</i>– Integrated space-group and crystal-structure determination

George M. Sheldrick · Acta Crystallographica Section A Foundations and Advances · 2014 · 28.6K citations · Full text

, , +16

van der Waals Volumes and Radii

A. Bondì · The Journal of Physical Chemistry · 1964 · 19.2K citations

, , +8

NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist

Gregory R. Fulmer, Alexander J. M. Miller, Nathaniel H. Sherden et al. · Organometallics · 2010 · 3.9K citations

, , +9

Atoms in molecules

R. F. W. Bader · Accounts of Chemical Research · 1985 · 3.7K citations

, , +17