Publication | Closed Access
Preventing Pd–NHC bond cleavage and switching from nano-scale to molecular catalytic systems: amines and temperature as catalyst activators
26
Citations
78
References
2019
Year
Chemical EngineeringEngineeringMolecular Pd/nhc CatalysisPd/nhc ComplexesCatalytic SynthesisOrganic ChemistryMolecular Catalytic SystemsNanocatalysisCatalysisOrganometallic CatalysisChemistryCatalyst ActivatorsCatalyst PreparationMolecular ComplexPd–nhc Bond CleavageMolecular CatalysisSecondary Aliphatic AminesBiomolecular Engineering
Heating Pd/NHC complexes with aliphatic amines induces Pd–NHC bond cleavage, while treating the complexes with primary or secondary aliphatic amines in the presence of strong bases promotes the activation of molecular Pd/NHC catalysis.
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