Chemical Communications · 2019 · 21 citations · 35 references
Natural SciencesChemical EngineeringChemistryCatalysisElectrochemistryInorganic ChemistryElectrode KineticsElectrode-electrolyte InterfacesWorking ElectrodesAdsorption At Electrochemical InterfacesElectrochemical ReductionElectrode Ion AdsorptionNitrate Reduction
is reversibly reduced at a mercury electrode, with a small prewave suggesting an adsorptive interaction between the complex and electrode surface. A catalytic current is observed in the presence of excess nitrate, with the onset potential for catalysis at the prewave. Nitrate is electrocatalytically reduced to nitrite, with preliminary mechanistic investigations implicating a chromium oxo intermediate.
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How a century of ammonia synthesis changed the world
Jan Willem Erisman, Mark A. Sutton, James N. Galloway et al. · Nature Geoscience · 2008 · 4.5K citations