Rechargeable Zn–MnO ₂ batteries: advances, challenges and perspectives

Abstract

As one type of advanced alternative batteries, zinc-ion batteries (ZIBs) have attracted increasing attention because of their advantages of cost-effectiveness, high safety and environmentally benign features. However, the performance of cathode materials has become a bottleneck for the future application of ZIBs. In recent years, manganese dioxide (MnO₂)-based materials as cathodes for ZIBs have been intensively explored. In this review, recent advances in MnO₂-based cathode materials for ZIBs are comprehensively reviewed with a discussion about the reaction mechanisms for the fundamental understanding of the electrochemical processes. Furthermore, several challenges hindering the technology maturity are also analyzed with corresponding strategies to further improve the electrochemical performance of such Zn-MnO₂ batteries.