Photoelectrochemical Bisphenol S Sensor Based on ZnO‐Nanoroads Modified by Molecularly Imprinted Polypyrrole

Roman Viter, Kwanele Kunene, Povilas Genys, Daniels Jevdokimovs, Donāts Erts, Andris Šutka, Krishna Bisetty, Artūrs Vīksna, Almira Ramanavičienė, Arūnas Ramanavičius

Macromolecular Chemistry and Physics · 2019 · 72 citations · 33 references

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Abstract

Abstract Molecularly imprinted polymers are important tools for the design of sensors and other molecular recognition based analytical systems. In this paper the development of a photoelectrochemical sensor for selective bisphenol determination is reported. The sensor is based on a glass/ZnO/MIP‐Ppy structure consisting of glass modified by a ZnO layer (glass/ZnO), which is functionalized by molecularly imprinted conducting polymer polypyrrole (MIP‐Ppy). The sensitivity of the sensor to bisphenol is in the range of 0.7–12.5 µ m . Selectivity tests to other bisphenolic compounds are performed. Some aspects of a photoinduced response mechanism in glass/ZnO/MIP‐Ppy nanostructures are predicted and discussed.

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